01
CONCEPT
Nucleus: Composition, Size & Nuclear Force
In one line
A nucleus is a tiny core of protons and neutrons. Its radius grows as A1/3, so its density is the same for all nuclei.
A nucleus is a tiny core of protons and neutrons. Its radius grows as A1/3, so its density is the same for all nuclei.
COMPOSITION
26.1.1 What a nucleus contains
Protons and neutrons are called nucleons
- Z = atomic number = number of protons.
- N = number of neutrons.
- A = mass number = number of nucleons.
- A nuclide is written AZX.
- A nucleus has no electrons.
TYPES OF NUCLEI
26.1.2 Isotopes, isobars and isotones
| Type | Same | Example |
|---|---|---|
| isotopes | Z | 11H, 21H, 31H |
| isobars | A | 31H, 32He |
| isotones | N = A − Z | 31H, 42He |
- Isotopes have the same chemical properties.
NUCLEAR SIZE
26.1.3 Radius from mass number
- R0 = 1.2 × 10−15 m = 1.2 fm.
- Volume ∝ R3 ∝ A.
R grows with A; density does not change
NUCLEAR DENSITY
26.1.4 Same for all nuclei
- m = mass of a nucleon = 1.67 × 10−27 kg.
- A cancels: ρ does not depend on A.
- ρ ≈ 2.3 × 1017 kg m−3.
BREAK-UP AT REST
26.1.5 Velocity and radius ratios
NUCLEAR FORCE
26.1.6 What holds nucleons together
- Strongest force in nature.
- Short range: acts only up to about 10−15 m.
- Attractive, and it makes the nucleus stable.
- Charge independent: same for p–p, n–n and p–n.
- Non-central; does not obey the inverse square law.
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The neutron
- Discovered by Chadwick. Charge zero, mass 1.675 × 10−27 kg.
- Present in every nucleus except ordinary hydrogen.
- Free neutron is unstable: half-life about 12 minutes.
- Decay: n → p + e− + ν̄.
Thermal neutrons
- A moderator (heavy water, graphite, paraffin wax) slows fast neutrons.
- Thermal neutron: energy about 0.025 eV, speed about 2.2 km s−1.
Mirror nuclei
- Same A, with Z and N interchanged.
- Example: 31H and 32He.
Exchange of mesons
- Nuclear force is an exchange force (Yukawa).
- p ↔ n: exchange of a charged π-meson (π+, π−).
- n–n and p–p: exchange of a neutral π-meson (π0).
02
CONCEPT
Mass Defect & Binding Energy
In one line
A nucleus weighs less than its separate nucleons. The missing mass is the energy that binds it.
A nucleus weighs less than its separate nucleons. The missing mass is the energy that binds it.
ATOMIC MASS UNIT
26.2.1 Mass and energy
| Particle | Mass (u) |
|---|---|
| electron | 0.0005486 |
| proton | 1.007276 |
| neutron | 1.00865 |
MASS DEFECT
26.2.2 Nucleus is lighter than its parts
- M = mass of the nucleus.
- Using atomic masses, use mH in place of mp.
BINDING ENERGY
26.2.3 Energy needed to pull a nucleus apart
- The same energy is released when the nucleus forms.
- Larger B.E. per nucleon ⇒ more stable nucleus.
BINDING ENERGY CURVE
26.2.4 B.E. per nucleon against A
Peak near A = 56; light nuclei fuse, heavy nuclei split
- Rises sharply for light nuclei.
- Maximum 8.8 MeV per nucleon at 56Fe.
- Falls slowly to 7.5 MeV at 238U.
- Nearly constant for A between 30 and 170.
- 4He, 12C, 16O lie above their neighbours.
STABILITY
26.2.5 Neutrons against protons
Heavy stable nuclei have N > Z
- Light stable nuclei: N ≈ Z.
- Heavy stable nuclei: N > Z; extra neutrons balance the electric repulsion.
- No stable nuclide has Z > 83.
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Pair production
A γ-photon near a nucleus creates e+ and e−
- Rest energy of each particle: 0.51 MeV.
- Minimum photon energy: 2 × 0.51 = 1.02 MeV.
- Reverse process, pair annihilation: e+ + e− → 2γ.
Packing fraction
f is zero near A = 16 and A = 240
- Can be positive, negative or zero.
- Smaller f ⇒ more stable nucleus.
Even and odd numbers
- Even Z, even N: most stable (about 60% of stable nuclides).
- Odd Z, odd N: least stable; only five such stable nuclides.
03
CONCEPT
Nuclear Reactions & Q-value
In one line
In a nuclear reaction A and Z are conserved. The change in mass appears as the energy Q.
In a nuclear reaction A and Z are conserved. The change in mass appears as the energy Q.
NUCLEAR REACTION
26.3.1 Writing a reaction
- Short form: X(a, b)Y.
- X = target, a = projectile, Y = product, b = emitted particle.
CONSERVATION LAWS
26.3.2 What stays the same
- Total mass number A.
- Total charge number Z.
- Momentum and total energy.
| Particle | Symbol |
|---|---|
| proton | 11p |
| neutron | 10n |
| deuteron | 21H |
| alpha | 42He |
| electron | 0−1e |
| positron | 0+1e |
Q-VALUE
26.3.3 Energy of the reaction
- Q > 0: exothermic, energy released.
- Q < 0: endothermic, energy absorbed.
- A free proton or neutron has zero binding energy.
DECAY AT REST
26.3.4 Sharing of energy
Parent at rest: momenta are equal and opposite
- Lighter particle takes more kinetic energy.
- Equal p ⇒ equal de Broglie wavelength.
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Recoil on emitting a photon
- The nucleus loses a little more than hν of internal energy.
Reactions with a moving projectile
- A reaction with Q < 0 needs Kp > |Q|.
Common reactions
- (α, p): 2He4 + 7N14 → 8O17 + 1H1 (Rutherford, 1919).
- (p, n): 1H1 + 5B11 → 6C11 + 0n1.
- (n, p): 0n1 + 7N14 → 6C14 + 1H1.
04
CONCEPT
Nuclear Fission & Fusion
In one line
Energy is released when nuclei move up the binding energy curve: heavy nuclei split, light nuclei join.
Energy is released when nuclei move up the binding energy curve: heavy nuclei split, light nuclei join.
TWO WAYS TO RELEASE ENERGY
26.4.1 Fission and fusion
| Fission | Fusion | |
|---|---|---|
| what happens | heavy nucleus splits | light nuclei join |
| example | U235 + n | 2H + 2H |
| condition | slow neutrons | very high temperature |
| energy from | mass defect | mass defect |
- Mass of products is less than the mass of reactants.
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Fission of uranium
Liquid drop picture: the nucleus stretches and splits
- Energy per fission ≈ 200 MeV, about 0.8 MeV per nucleon.
- Average 2.5 neutrons per fission, each about 2 MeV (fast).
- U235 fissions with slow neutrons; most of the energy is KE of the fragments.
- Explained by Bohr and Wheeler (liquid drop model).
Chain reaction
Each fission can start three more
| k | Chain reaction | Size |
|---|---|---|
| k = 1 | steady (reactor) | critical |
| k > 1 | accelerates (atom bomb) | super-critical |
| k < 1 | dies out | sub-critical |
Nuclear reactor
Parts of a reactor
| Part | Job | Example |
|---|---|---|
| fuel | undergoes fission | U235, Pu239 |
| moderator | slows neutrons | graphite, heavy water |
| control rods | absorb neutrons | cadmium |
| coolant | carries away heat | water, CO2 |
| shield | stops radiation | thick concrete |
Fusion and stars
Nuclei must overcome electric repulsion
- Needs about 107 K to 108 K and high pressure: thermonuclear reaction.
- Proton-proton chain in the Sun:
| Atom bomb | Hydrogen bomb |
|---|---|
| fission | fusion |
| critical size matters | no limit of size |
| normal temperature and pressure | high temperature and pressure |
| less energy | more energy |
05
CONCEPT
Radioactive Decays: Alpha, Beta, Gamma
In one line
An unstable nucleus emits α, β or γ on its own. Each emission changes A and Z in a fixed way.
An unstable nucleus emits α, β or γ on its own. Each emission changes A and Z in a fixed way.
RADIOACTIVITY
26.5.1 A property of the nucleus
- Spontaneous emission of radiation by heavy nuclei (Becquerel, 1896).
- A nuclear event: the electrons play no part.
- Not affected by pressure, temperature, fields or chemical state.
- Elements with Z > 82 are naturally radioactive.
THE THREE RADIATIONS
26.5.2 α, β and γ
In a magnetic field α and β bend opposite ways; γ goes straight
| Feature | α | β | γ |
|---|---|---|---|
| nature | He nucleus | fast electron | photon |
| charge | +2e | −e | 0 |
| speed | about 107 m s−1 | up to 0.99c | c |
| penetration | 1 | 100 | 10,000 |
| ionisation | 10,000 | 100 | 1 |
| in E or B field | deflected | deflected | not deflected |
| energy spectrum | line | continuous | line |
- Penetrating power: γ > β > α.
- Ionising power: α > β > γ.
DISPLACEMENT LAWS
26.5.3 Change in A and Z
| Emission | A | Z | N |
|---|---|---|---|
| α | A − 4 | Z − 2 | N − 2 |
| β− | A | Z + 1 | N − 1 |
| β+ | A | Z − 1 | N + 1 |
| γ | A | Z | N |
USEFUL RESULTS
26.5.4 Isotopes and isobars
- One α + two β− ⇒ isotope of the parent (A falls by 4).
- One β− or one β+ ⇒ isobar of the parent.
- γ emission ⇒ same nucleus at a lower energy.
COUNTING α AND β
26.5.5 Parent to final nucleus
- Find nα first; only α changes A.
- Example: 238U → 206Pb gives 8α and 6β.
β-DECAY
26.5.6 Where the electron comes from
- The electron is created in the nucleus; it was not there before.
- A free neutron decays because mn > mp.
- A proton turns into a neutron only inside a nucleus.
- ν and ν̄ have no charge and almost no mass.
β energies are continuous up to a maximum; the neutrino shares the energy
γ-DECAY
26.5.7 Nucleus falls to a lower level
- Follows α or β decay, from an excited nucleus.
- Nuclear levels are about 1 MeV apart; atomic levels about 1 eV.
- So γ-rays have far smaller wavelength than visible light.
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Absorption of γ-rays
- x = thickness, μ = absorption coefficient.
Electron capture
- An inner electron joins a proton in the nucleus: p + e− → n + ν.
- Happens when β+ emission is not energetically possible.
Radioactive series
| Series | Parent | End |
|---|---|---|
| 4n (thorium) | 232Th | 208Pb |
| 4n + 1 (neptunium) | 237Np | 209Bi |
| 4n + 2 (uranium) | 238U | 206Pb |
| 4n + 3 (actinium) | 235U | 207Pb |
06
CONCEPT
Law of Radioactive Decay: Half-life & Mean Life
In one line
The rate of decay is proportional to the number of nuclei left, so N falls exponentially and halves every T.
The rate of decay is proportional to the number of nuclei left, so N falls exponentially and halves every T.
DECAY LAW
26.6.1 Rutherford and Soddy
- N0 = nuclei at t = 0; N = nuclei left at time t.
- λ = decay constant: probability of decay per unit time.
- Decayed nuclei = N0 − N.
- λ depends only on the nuclide, not on N or on conditions.
HALF-LIFE
26.6.2 Time to reduce to half
N halves in every interval T
- Works for mass and activity too.
- n need not be a whole number: n = 32 gives 12√2.
| Time | Fraction left | Fraction decayed |
|---|---|---|
| T | 12 (50%) | 12 (50%) |
| 2T | 14 (25%) | 34 (75%) |
| 3T | 18 (12.5%) | 78 (87.5%) |
| 4T | 116 (6.25%) | 1516 (93.75%) |
TIME BETWEEN TWO STAGES
26.6.3 Use the fraction left
- Always turn "% decayed" into "% left" first.
- Example: 40% decayed to 85% decayed means 60% left to 15% left, a factor of 4, so 2T.
- If e−λt = x, then after half the time the fraction is √x.
MEAN LIFE
26.6.4 Average life of a nucleus
After one mean life 37% is left
- At t = τ: N = N0e = 0.37 N0 (37% left, 63% decayed).
- At t = 2τ: N = N0e2 = 0.135 N0.
- Mean life is greater than half-life.
STRAIGHT-LINE GRAPH
26.6.5 Finding λ
Plot of ln of (N ÷ N0) against t: slope −λ
- τ = size of 1slope.
07
CONCEPT
Activity, Comparing Samples & Dating
In one line
Activity is the decay rate A = λN. It falls just like N, and it lets us compare samples and find ages.
Activity is the decay rate A = λN. It falls just like N, and it lets us compare samples and find ages.
ACTIVITY
26.7.1 Decays per second
- Units: 1 Bq = 1 decay per second.
- 1 Rd = 106 decays per second.
- 1 Ci = 3.7 × 1010 decays per second.
- Between two times: A1A2 = eλ(t2 − t1).
USEFUL RESULTS
26.7.2 Asked often
- Activity falls to 1x in time t ⇒ it falls to 1xn in time nt.
- A0A = e at t = t′ ⇒ λ = 1t′, T = t′ ln 2.
- Rate of change of activity ∝ λ2 ∝ T−2.
- m = mass of the sample, M = atomic weight, NA = Avogadro number.
- Use T in seconds for an answer in Bq.
COMPARING TWO SAMPLES
26.7.3 Ratio of activities
Larger λ: starts faster, falls sooner
- Half-life of a sample: T ∝ N ÷ A.
SAME START, DIFFERENT λ
26.7.4 Ratio of nuclei left
- Put the ratio as a power of e and compare the powers.
- With half-lives: count half-lives of each sample separately.
- Decayed numbers: use 1 − fraction left for each.
- If T of A = τ of B, then λA = 0.693 λB: B decays faster.
PARALLEL DECAY
26.7.5 One nucleus, two processes
A can decay in either of two ways
SUCCESSIVE DECAY
26.7.6 A → B → C
A falls, B rises then falls, C keeps rising
- So NANB = λ2λ1 = T1T2.
DAUGHTER AND PARENT
26.7.7 Finding time from a ratio
- Y is stable and comes only from X.
- Ratio X : Y = 1 : 7 ⇒ X is 18 of the start ⇒ t = 3T.
RADIOACTIVE DATING
26.7.8 Age from activity
- Carbon-14 (T = 5730 years) for wood and bones.
- A0 = activity of a fresh sample of the same size.
- Uranium and lead for rocks and the earth.
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Production at a steady rate
- P = nuclei produced per second; N starts from zero and tends to P ÷ λ.
Uses of radioactive isotopes
- Medicine: cobalt-60 (cancer), iodine-131 (thyroid), sodium-24 (blood circulation).
- Archaeology: carbon-14 dating; uranium-lead for rocks.
- Agriculture: cobalt-60 preserves potato crops; phosphorus-32 in fertilisers.
- Tracers: leaks in pipes, biochemical reactions.
EXAM-DAY CARD
Just see this before the exam
R = R0A1/3
size
B.E. = Δm × 931
binding energy
Q = Δm c2
reactions
nα = A − A′4
decays
N = N0(12)t/T
half-life
A = λN
activity
FORMULA SHEET
Whole chapter on one page
Nucleus
A = Z + N
R = R0A1/3, R0 = 1.2 fm
ρ ≈ 2.3 × 1017 kg m−3
R1R2 = (v2v1)1/3
Binding energy
1 u = 931 MeV
Δm = Zmp + Nmn − M
B.E. = Δm × 931 MeV
peak 8.8 MeV at 56Fe
Reactions
A and Z conserved
Q = (min − mout) × 931
Q = B.E.out − B.E.in
Kα = Q(A − 4)A
Decays
α: A − 4, Z − 2
β−: Z + 1; β+: Z − 1
nα = A − A′4
nβ = 2nα − (Z − Z′)
Decay law
N = N0e−λt
N = N0(12)t/T
T = 0.693λ
τ = 1λ = 1.44 T
Activity
A = λN = A0e−λt
A1A2 = N1T2N2T1
N1N2 = e−(λ1 − λ2)t
parallel: λ = λ1 + λ2
TOP MISTAKES
Avoid these = easy marks
MISTAKE ✗
Density depends on A
"% decayed" used as "% left"
β− lowers Z
T = 1λ
CORRECT ✓
Mass and volume both ∝ A: ρ constant
Left = 100% − decayed
β−: Z + 1; β+: Z − 1; A same
T = 0.693λ; τ = 1λ